First, I am assuming that the pics you sent are all from the right side. I see some evidence of a blown gasket, but really think that the valves should be able to go back in just the way they are. Bring the piston up to TDC level with the top of the block. I would scrap the top of the piston carefully with a putty knife, no gouges. After scraping clean the top of the piston. I use 0000 steel wool and carb cleaner, but can use any type of cleaner which will do the job. Also clean the area where the gasket was attached. After you have cleaned the piston, move it down to BDC and clean the inside of the cylinder. I start with a soft rag a light cleaning solvent (nothing harsh), just something to get it clean. Many people like to use a lubricant like WD-40 which will clean and protect. After cleaning dry with a soft rag and apply a thin coat of motor oil to prevent corrosion while it is standing open.
As for the head the only thing I would do there is clean the gasket surfaces, and leave the valves alone. If you want to tackle the other side go for it. Any time you let it sit cover with rags. Now would also be a good time to order the gaskets you will need. Your supplier may have to order some not in stock. I suggest head gaskets, valve cover gaskets (if they are used, some use an RTV sealant), intake and exhaust gaskets, any you have removed. Also, clean the head bolts. Any other questions at this point?