Sitting in traffic would only be a problem from sniffing unburned fuel as far as lead goes & you would have to sniff a lot of it.
Nitrogen oxides is what makes you sick in heavy traffic and on still days, straight lack of oxygen &/or CO & CO2 posioning
On a still day the O2 content of air can drop down to levels low enough to render people unconscious
Once the lead has been through you engine what comes out of the tailpipe is totally inert.
IT is also very hot so rises up into the air,and can travel for miles..
The lead on the side of the road is from paint dust and from tires.
All of the tests are fudged because they are only testing for lead and not what compound the lead is in or it's valence state.
So I can pass the dust through an Acetylene - Nitrous flame and get a lead reading but that lead can never be adsorbed by your body.
You test for lead posioning by doing urine & stool analysis because the body is removing the lead all by itself.
You screen for lead posioning by doing hemaglobens which will go down as the lead binds the oxygen in your blood.
After that it is a urinary ALA then if that looks bad a full chemical blood analysis.
You get more lead from cheap Chinese & Mexican pottery than you would ever have gotten from the tetra-ethyl lead used in fuels .
Lead solder used to seal cans firstly does not get to the food, secondly does not dissolve into the food & thirdly would go strait through the body if it did.
The only environmental risk would be to the cannery workers breathing the fume off the lead on very old lines where molten lead is used.
Th more modern plants put a ribbon of lead between the top & side then rolls them together twice, the heat from this is generally enough to melt the solder .
They dug up some lead lined cans of beef from Napoleons venture into Russia in 1975 and to every ones surprise the beef was still quite editable .
OTOH the supposedly "safe" lead free solder used in modern cans can not make the same long term seal and canned foods go off very quickly, particularly canned fruits where the juices are quite acidic, so people are posioned on a daily basis from the new "safe" cans because they leak .
Your gut is hydrochloric acid and prior to the invention of fiberglass , bulk hydrochloric acid was shipped in lead lined steel containers because lead is totally insoluable in hydrochloric acid .
As mentioned previously lead is soluable in carbonic acid formed by rain passing through CO2 but you would have to drink 1,000,000 gallons to get a dose that may cause problems.
It only takes about 2 weeks for a badly leaded furnace man with a hemogloben of 5 to recover from lead exposure and get back into the teens .
The lead oxides are tough and really not simple acid soluable remember they do not dissolve in battery acid either . You use nitric acid or better still aqua rega to dissolve lead .
How many times have you needed to scrape a battery terminal to get a good electrical connection because the surface had oxadised ?
Some oxides are tough and bound very strong, like lead & stainless steel which we are all familiar with.
Others are quite loose, adsorb water and flake off like red rust Fe203 or white aluminium oxide Al2 O3 -6H20
Mill scale ( FeO ) is formed at a much higher temperature than rust Fe203 and is tough and not water soluable
It is all about the entropy ( energy used in to formation ) and basically if you put a lot of energy in to make a stable compound then it takes more energy to break it down.
All metal oxides are posionous, electrical & thermal insulators & abrasive.
Take too many antacid tablets ( MgO ) and you are in for a stomach pump yet a couple will settle a bloated stomach quite happily.
IT is all about the valence state of the metal ions and the strength of the bonds
Chromium 1 & 2 are fine but Cr6 is fatal in trace amounts