I had a guy tell me that starting fluid would blow up an engine. I disconnected the fuel pump on a Briggs OHV twin and gave him a can and told him to try and blow it up. He used the whole can and couldn't blow it up.
Been a fun thread pursuing an urban legend. What's next? Does a mower run "better" on premium vs regular?
All I know is you don't want to try that on a two cycle engine. I prefer to use whatever the engine is design to run on as the test fuel. But starter fluid is a lazy and convenient way of testing as it is something easily reached for. There haven't been a can of the stuff in my shop in many years other than when a can comes on a customer's mower. As for my shop there hasn't been a can of carburetor cleaner in my shop since 2014. I actually gave my last can drip cleaner back in late 2014. I am cleaning carburetors every week here lately.
Most 4 cycle small engines on lawn care equipment usually have a fairly low compression ratio. Now higher compression engines may have a problem with starter fluid use due it being more volatile than gasoline. Tighter the confined space the more explosive it becomes.
But of a full gas tank is less likely to explode than a near empty one as fuel vapor is more volatile than liquid fuel in a sealed container with a spark introduced.
I was surprised the customer's Kawasaki 3010 didn't catch a fire from the leaky fuel pump as it was leaking on the pressure regulator side of the fuel pump where there is was open contacts, loose ground wire, and a bare hot lead. Another great DIYer rigged job. The DIYer rather risk things instead putting on a $25 electric fuel pump. But of course the idiot use Motoseal RTV to seal the carburetor and to patch up leaky engine gaskets. It ended up costing the new owner over $1800 in repairs and he still has the brakes to repair. He just wanted me to get the 3010 running again. He said his son can fix the brakes. That is fine with me as I done spent 18 hours repairing the 3010 engine and the CV axles. A royal pain to remove and install the engine. It was the first engine I repair that didn't have an internal governor; the governor is in the gearbox.