Any metal to metal contact has the ability to create a tight bond as it rusts together. It doesn't take much rust to seize a bolt and it's the rust you don't see that causes the problem. When this happens, you must break the bond between the two metals to get the bolt free. Heating up the bolt so that it swells can and does break the bond, but not always. Hitting the hot parts with penetrating lubricant will cause metals to shrink and often will suck some of the penetrant deep into the threads. It might take more than one or two cycles of heat and cold to get the bond to break. Steel also becomes plastic with heat. Heat the head enough, and the bolt will stretch a bit, releasing any pressure. You can argue with the physics all you want, but that's how it works. We call it the "hot wrench" for a reason. Do be careful though... heat can and will be transmitted through all metals and things like seals can be adversely affected. Just use reasonable care and you should be fine.
However, the absolute best way to bust things loose is prevention, prevention, prevention. Using anti-seize is an easy, cheap and incredibly effective way to prevent metals from creating any kind of bond. The carrier (grease) used in anti-seize will keep water out preventing any rust. In addition, the tiny, tiny flecks of a disimilar metal that can't rust does the rest and will continue to act as a lubricant should the grease dry out. Yeah, you don't like this and yet it seems that you have more than your share of stuck bolts. Perhaps you should give it a try. What have you got to loosen???
I was, at one time, an ASE Master Certified Auto & Truck Technician. My first job in the automotive world was back in 1969 and I spent 30 years in the service bays and learned how to deal with stubborn fasteners. I even moon lighted as a small engine mechanic and have never, ever met a blade bolt that would not come off. I'm the guy people would take their broken bolts to, because I know how to get them free without ruining the part.
Since I have been repairing mowers for a living I would have replaced several thousand blade bolts and am yet to come across one with the slightest amount of corrosion on them apart from on the outside of the head where they are exposed to the acid from the cut grass. They lock in because they self tighten in use .
It is a pure a simple case of dynamic loads causing the blade to rotate on the spindle and because the bolt head can not slip on the blade as it is under spring tension the bolt tightens.
This is also plain physics, the spindle is rotating in one direction and the blades resist the rotation so tighten .
Blade bolts fitted into a spindle never ever rust solid in place.
They can not do this unless fitted wet as the hole is blind , points up and the spindle / blade / washer / bolt interface is airtight when done up to the recommended torque.
Blade carriers on the other hand do rust in place because they are open to the atmosphere so you can get an oxidizing agent in there, usually water to start a galvanic cell and allow corrosion to occur
Or if you want to sound knowlegable, allow the high energy steel to revert to a lower energy state according to the laws of thermodynamics.
metals that have the same crystal structure or are in fact the same will form oxides that will grow into each other and form a single oxide layer.
Weather this is a problem depends upon thinsg like the strength of the oxide and the volume increase of the oxide, which in the case of rust is the big problem as rust is very very weak.
This is usually not a big problem unless it is a metal like stainless steel where the oxide is particularly strong, we call this gauling if it is on a fastener or stiction if it is something that is supposed to be a sliding fit.
Zinc carb slides are notorious for stiction & stainless bolts for gauling but neither of these are applicable to blade bolts .
Heating nuts & bolts works because one part gets heated more than the other part so it moves with respect to the other part and this movement can cause a fracture line to happen through one of the oxide to metal interfaces if and only if the amount of differential movement is sufficient .however, if not heated to red hot where a phase change causes a massive volume change, the amount of actual expansion is quite small. Like every process it has places where it is very appropriate and places where it actually makes the problem worse and a blade bolt is one of these cases.
I do use grease , copper, nickel & graphite anti sieze but being properly trained,only in places where it is appropriate to do so and then because I am properly trained the tension applied to the fastener is reduced to the appropriate level to compensate for the reduction in the dynamic friction between the contact faces of the threads .
A blade bolt into a spindle is not an appropriate place to use any type of thread lubricant because it MAKES THE SELF TIGHTENING WORSE even if the fastener was only tightened to 62.5 % of the printed dry thread torque to compensate for using copper anti sieze .
If the bolt is done up to the full listed tension then it will already be over tight and unless the anti sieze was also under the head, where it should never go the bolt will be a lot harder to remove and you run the risk of breaking the bolt because they are only grade 5 ( on commercial ) or standard ( on domestic) grade bolts thus you run the real risk of necking the shaft under the head thus allowing the bolt to fail under use.
Now I rarely bother to play the "qualificatins game" on the web because readers should read all of what is posted then make up their own minds not blindly follow the person with the higher quaifications.
But as you think it is appropriate I started off my career as a metallurgist, graduating with a higher diploma, followed with an undregraduate degree in metallurgy and one year of a masters in materials science which I never got around to fininshing .
Add to that post graduate diplomas in NDT and a stand alone radiology diploma , followed by a radiation diploma so I could rent isotopes to x-ray welds in pipes followed by a diploma in accoustic emissions , then audiology
diploma ( for workers comp ) and a diploma in adult eduction so could teach TAFE students part time. to be able to sign off on defense work NATA required me to get further qualifications in microscopy & metallography so as one of my ex- business partners used to say, more degrees than a thermometer .
But again people should read a post , work it through for themselves then try what they think is appropriate as this is the web & I could really be a 12 year old girl who gets her jollies by fooling people on line.