My guess is that you're too young to remember cars without computer control, or you'd remember "pinging" issues, or cars that would "diesel" after being turned off for up to a full minute. These were common occurrences when you switched to a different octane, and don't happen on today's cars because of computers.
But to your other question, 91 octane at your local gas station has the ethanol, and I believe the OP was referring to a marina that has ethanol free. Try Google and look for "ethanol free gasoline" and you may come up with something. For example, when I checked a couple years ago, there was a station in my state that had it. And it was only 250 miles away.