First -
Rule of thumb -If the blade tips on ANY mower's blades can be within 1/4 inch of each other while rotating, offset one from the other by 90 degrees. Some mowers require this - consult your owner's manual or go to your manufacturer's web site and look up your model.
Following the offset rule, for a three blade deck:
Make the Left and Right blades face North/South (i.e. Front-to-Back) and
make the middle blade face East-West (Left-to-Right).
Yes, belts can slip but at least you started with the most seperation possible and if the belts slip 90 degrees worth, you have a larger issue.