A thermoset is a polymer that forms irreversible chemical bonds during the curing process. Unlike thermoplastics that can be melted and remould multiple times, thermosets (as their names suggest) are set in a permanent physical and chemical composition after the first curing process. This occurs as polymers in the material ‘cross-link’, performing an unbreakable, irreversible bond. This unique feature makes thermosetting polymers an excellent choice for parts that need to have excellent dimensional stability at elevated temperatures.
The critical difference between thermoplastics and thermosets is how the materials behave during the curing process. Thermosets strengthen when cured but form chemical bonds that make them impossible to remould. Thermoplastics do not form any chemical bond when curing, making them re-mouldable and recyclable. This three-dimensional bonding in thermosets makes them stronger and more heat resistant than thermoplastics.
Thermosets' ability to retain their strength and geometry when exposed to elevated temperatures set them apart from thermoplastics. Thermosets will often degrade before melting when exposed to excess heat. These properties mean plastics can be used as a low-cost replacement for metals in some applications.
In a nutshell, thermosets generally have greater physical properties than thermoplastics; however they cannot be remoulded and recycled.