You can be shocked by 12VDC, or even less. Grab a new 9V battery and touch it to your tongue. Now touch it to your hand. Tongue = low enough resistance that OUCH!
Hand = high enough resistance that no perceptible shock takes place.
This is also why birds and squirrels can sit on power lines without being shocked. They are exposed to voltages from 7.2kV to 33kV without any issues, because they are isolated from ground and all other phases. Occasionally, a squirrel will step from the line to the pole rather than jumping, at which time we have to take a moment of silence and hope that particular tree rat made his peace with Jesus.
I did get a tingle from a truck 12v battery one time, i was soaked with sweat (water) and i was leaning over the engine bay, and touched my forearm to + and - and it tingled me enough to where i wondered "What the heck was that!?"