You are correct when the head overheats the guides move up inside the springs toward the spring cap and keeper until the rocker arm tries to push the valve open and the valve stem cap hits the rocker and the push rod bends. In some cases the valve guide will move up to within 1/4 inch of the valve stem cap. Compare the height of the valve guides in the head and it should be easy to spot if one has moved since both guides should be the same height. Exhaust valve guide will be the one to move which would be the valve closest to the muffler exhaust pipes.